New opportunities for sustainable bioplastic development: Tailorable polymorphic and three-phase crystallization of stereocomplex polylactide by layered double hydroxide

Research output: Contribution to journal › Journal article › Research › peer-review

Standard

New opportunities for sustainable bioplastic development : Tailorable polymorphic and three-phase crystallization of stereocomplex polylactide by layered double hydroxide. / Chen, Qi; Auras, Rafael; Corredig, Milena; Kirkensgaard, Jacob Judas Kain; Mamakhel, Aref; Uysal-Unalan, Ilke.

In: International Journal of Biological Macromolecules, Vol. 222, 2022, p. 1101-1109.

Research output: Contribution to journal › Journal article › Research › peer-review

Harvard

Chen, Q, Auras, R, Corredig, M, Kirkensgaard, JJK, Mamakhel, A & Uysal-Unalan, I 2022, 'New opportunities for sustainable bioplastic development: Tailorable polymorphic and three-phase crystallization of stereocomplex polylactide by layered double hydroxide', International Journal of Biological Macromolecules, vol. 222, pp. 1101-1109. https://doi.org/10.1016/j.ijbiomac.2022.09.205

APA

Chen, Q., Auras, R., Corredig, M., Kirkensgaard, J. J. K., Mamakhel, A., & Uysal-Unalan, I. (2022). New opportunities for sustainable bioplastic development: Tailorable polymorphic and three-phase crystallization of stereocomplex polylactide by layered double hydroxide. International Journal of Biological Macromolecules, 222, 1101-1109. https://doi.org/10.1016/j.ijbiomac.2022.09.205

Vancouver

Chen Q, Auras R, Corredig M, Kirkensgaard JJK, Mamakhel A, Uysal-Unalan I. New opportunities for sustainable bioplastic development: Tailorable polymorphic and three-phase crystallization of stereocomplex polylactide by layered double hydroxide. International Journal of Biological Macromolecules. 2022;222:1101-1109. https://doi.org/10.1016/j.ijbiomac.2022.09.205

Author

Chen, Qi ; Auras, Rafael ; Corredig, Milena ; Kirkensgaard, Jacob Judas Kain ; Mamakhel, Aref ; Uysal-Unalan, Ilke. / New opportunities for sustainable bioplastic development : Tailorable polymorphic and three-phase crystallization of stereocomplex polylactide by layered double hydroxide. In: International Journal of Biological Macromolecules. 2022 ; Vol. 222. pp. 1101-1109.

Bibtex

@article{41d9495afd62424dafd7496719467a07,
title = "New opportunities for sustainable bioplastic development: Tailorable polymorphic and three-phase crystallization of stereocomplex polylactide by layered double hydroxide",
abstract = "Stereocomplexation between enantiomeric poly(L-lactide) (PLLA) and poly(D-lactide) (PDLA) is a promising sustainable approach and gaining momentum to overcome the shortcomings of polylactide (PLA) for its use as a replacement for fossil-based plastics. Filler addition in tailoring the crystallization of stereocomplex PLA (SCPLA) has attracted extensive attention; however, research has primarily focused on the heterogeneous nucleation effect of filler. The impact of filler on the chain behavior of SC-PLA during crystallization has not been exclusively discussed, and the rigid amorphous fraction (RAF) development remains unknown. In this study, the crystallization of PLLA/PDLA blends was modified by low loading of layered double hydroxide (LDH) (",
keywords = "2D nanoparticle, Polymer nanocomposites, RAF, Nucleation, Thermal fluctuation, ENANTIOMERIC POLY(LACTIC ACID)S, CRYSTAL NUCLEATION, POLYMER LAYER, BLENDS, MORPHOLOGY, POLY(L-LACTIDE), NANOPARTICLES, TRANSITION, BEHAVIOR, SURFACE",
author = "Qi Chen and Rafael Auras and Milena Corredig and Kirkensgaard, {Jacob Judas Kain} and Aref Mamakhel and Ilke Uysal-Unalan",
year = "2022",
doi = "10.1016/j.ijbiomac.2022.09.205",
language = "English",
volume = "222",
pages = "1101--1109",
journal = "International Journal of Biological Macromolecules",
issn = "0141-8130",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - New opportunities for sustainable bioplastic development

T2 - Tailorable polymorphic and three-phase crystallization of stereocomplex polylactide by layered double hydroxide

AU - Chen, Qi

AU - Auras, Rafael

AU - Corredig, Milena

AU - Kirkensgaard, Jacob Judas Kain

AU - Mamakhel, Aref

AU - Uysal-Unalan, Ilke

PY - 2022

Y1 - 2022

N2 - Stereocomplexation between enantiomeric poly(L-lactide) (PLLA) and poly(D-lactide) (PDLA) is a promising sustainable approach and gaining momentum to overcome the shortcomings of polylactide (PLA) for its use as a replacement for fossil-based plastics. Filler addition in tailoring the crystallization of stereocomplex PLA (SCPLA) has attracted extensive attention; however, research has primarily focused on the heterogeneous nucleation effect of filler. The impact of filler on the chain behavior of SC-PLA during crystallization has not been exclusively discussed, and the rigid amorphous fraction (RAF) development remains unknown. In this study, the crystallization of PLLA/PDLA blends was modified by low loading of layered double hydroxide (LDH) (

AB - Stereocomplexation between enantiomeric poly(L-lactide) (PLLA) and poly(D-lactide) (PDLA) is a promising sustainable approach and gaining momentum to overcome the shortcomings of polylactide (PLA) for its use as a replacement for fossil-based plastics. Filler addition in tailoring the crystallization of stereocomplex PLA (SCPLA) has attracted extensive attention; however, research has primarily focused on the heterogeneous nucleation effect of filler. The impact of filler on the chain behavior of SC-PLA during crystallization has not been exclusively discussed, and the rigid amorphous fraction (RAF) development remains unknown. In this study, the crystallization of PLLA/PDLA blends was modified by low loading of layered double hydroxide (LDH) (

KW - 2D nanoparticle

KW - Polymer nanocomposites

KW - RAF

KW - Nucleation

KW - Thermal fluctuation

KW - ENANTIOMERIC POLY(LACTIC ACID)S

KW - CRYSTAL NUCLEATION

KW - POLYMER LAYER

KW - BLENDS

KW - MORPHOLOGY

KW - POLY(L-LACTIDE)

KW - NANOPARTICLES

KW - TRANSITION

KW - BEHAVIOR

KW - SURFACE

U2 - 10.1016/j.ijbiomac.2022.09.205

DO - 10.1016/j.ijbiomac.2022.09.205

M3 - Journal article

C2 - 36174869

VL - 222

SP - 1101

EP - 1109

JO - International Journal of Biological Macromolecules

JF - International Journal of Biological Macromolecules

SN - 0141-8130

ER -

ID: 323972631