Radiation-induced alteration of apatite on the surface of Mars: first in situ observations with SuperCam Raman onboard Perseverance

Research output: Contribution to journalJournal articleResearchpeer-review

Standard

Radiation-induced alteration of apatite on the surface of Mars : first in situ observations with SuperCam Raman onboard Perseverance. / Clavé, E.; Beyssac, O.; Bernard, S.; Royer, C.; Lopez-Reyes, G.; Schröder, S.; Rammelkamp, K.; Forni, O.; Fau, A.; Cousin, A.; Manrique, J. A.; Ollila, A.; Madariaga, J. M.; Aramendia, J.; Sharma, S. K.; Fornaro, T.; Maurice, S.; Wiens, R. C.; Acosta-Maeda, Tayro; Agard, Christophe; Alberquilla, Fernando; Alvarez Llamas, Cesar; Anderson, Ryan; Applin, Daniel; Aramendia, Julene; Arana, Gorka; Beal, Roberta; Beck, Pierre; Bedford, Candice; Benzerara, Karim; Bernard, Sylvain; Bernardi, Pernelle; Bertrand, Tanguy; Beyssac, Olivier; Bloch, Thierry; Bonnet, Jean-Yves; Bousquet, Bruno; Boustelitane, Abderrahmane; Bouyssou Mann, Magali; Brand, Matthew; Cais, Philippe; Caravaca, Gwenael; De Pinedo, Kepa Castro Ortiz; Cazalla, Charlene; Charpentier, Antoine; Chide, Baptiste; Clavé, Elise; Clegg, Samuel; Cloutis, Ed; Coloma, Leire; Comellas, Jade; Connell, Stephanie; Cousin, Agnes; DeFlores, Lauren; Dehouck, Erwin; Delapp, Dot; Perez, Tomas Delgado; Deron, Robin; Donny, Christophe; Doressoundiram, Alain; Dromart, Gilles; Essunfeld, Ari; Fabre, Cecile; Fau, Amaury; Fischer, Woodward; Follic, Hugo; Forni, Olivier; Fouchet, Thierry; Francis, Raymond; Frydenvang, Jens; Gabriel, Travis; Gallegos, Zachary; García-Florentino, Cristina; Gasda, Patrick; Gasnault, Olivier; Gibbons, Erin; Gillier, Martin; Gomez, Laura; Gonzalez, Sofia; Grotzinger, John; Huidobro, Jennifer; Jacob, Xavier; Johnson, Jeffrey; Kalucha, Hemani; Kelly, Evan; Knutsen, Elise; Lacombe, Gaetan; Lamarque, Florentin; Lanza, Nina; Larmat, Carene; Laserna, Javier; Lasue, Jeremie; Le Deit, Laetitia; Le Mouelic, Stephane; Legett, Chip; Leveille, Richard; Lewin, Eric; Little, Cynthia; Loche, Mattéo; Lopez Reyes, Guillermo; Lorenz, Ralph; Lorigny, Eric; Madariaga, Juan Manuel; Madsen, Morten; Mandon, Lucia; Manelski, Henry; Mangold, Nicolas; Martinez, Jose Manrique; Martin, Noah; Martinez Frias, Jesus; Maurice, Sylvestre; Mcconnochie, Timothy; McLennan, Scott; Melikechi, Noureddine; Meslin, Pierre Yves; Meunier, Frederique; Mimoun, David; Montagnac, Gilles; Montmessin, Franck; Moros, Javier; Mousset, Valerie; Murdoch, Naomi; Nelson, Tony; Newell, Ray; Nicolas, Cécile; Newsom, Horton; O’Shea, Colleen; Ollila, Ann; Pantalacci, Philippe; Parmentier, Jonathan; Peret, Laurent; Perrachon, Pascal; Pilleri, Paolo; Pilorget, Cédric; Pinet, Patrick; Poblacion, Iratxe; Poulet, Francois; Quantin Nataf, Cathy; Rapin, William; Reyes, Ivan; Rigaud, Laurent; Robinson, Scott; Rochas, Ludovic; Root, Margaret; Ropert, Eloise; Rouverand, Léa; Royer, Clement; Perez, Fernando Rull; Said, David; Sans-Jofre, Pierre; Schroeder, Susanne; Seel, Fabian; Sharma, Shiv; Sheridan, Amanda; Sobron Sanchez, Pablo; Stcherbinine, Aurélien; Stott, Alex; Toplis, Michael; Turenne, Nathalie; Veneranda, Marco; Venhaus, Dawn; Wiens, Roger; Wolf, Uriah; Zastrow, Allison.

In: Scientific Reports, Vol. 14, 11284, 2024.

Research output: Contribution to journalJournal articleResearchpeer-review

Harvard

Clavé, E, Beyssac, O, Bernard, S, Royer, C, Lopez-Reyes, G, Schröder, S, Rammelkamp, K, Forni, O, Fau, A, Cousin, A, Manrique, JA, Ollila, A, Madariaga, JM, Aramendia, J, Sharma, SK, Fornaro, T, Maurice, S, Wiens, RC, Acosta-Maeda, T, Agard, C, Alberquilla, F, Alvarez Llamas, C, Anderson, R, Applin, D, Aramendia, J, Arana, G, Beal, R, Beck, P, Bedford, C, Benzerara, K, Bernard, S, Bernardi, P, Bertrand, T, Beyssac, O, Bloch, T, Bonnet, J-Y, Bousquet, B, Boustelitane, A, Bouyssou Mann, M, Brand, M, Cais, P, Caravaca, G, De Pinedo, KCO, Cazalla, C, Charpentier, A, Chide, B, Clavé, E, Clegg, S, Cloutis, E, Coloma, L, Comellas, J, Connell, S, Cousin, A, DeFlores, L, Dehouck, E, Delapp, D, Perez, TD, Deron, R, Donny, C, Doressoundiram, A, Dromart, G, Essunfeld, A, Fabre, C, Fau, A, Fischer, W, Follic, H, Forni, O, Fouchet, T, Francis, R, Frydenvang, J, Gabriel, T, Gallegos, Z, García-Florentino, C, Gasda, P, Gasnault, O, Gibbons, E, Gillier, M, Gomez, L, Gonzalez, S, Grotzinger, J, Huidobro, J, Jacob, X, Johnson, J, Kalucha, H, Kelly, E, Knutsen, E, Lacombe, G, Lamarque, F, Lanza, N, Larmat, C, Laserna, J, Lasue, J, Le Deit, L, Le Mouelic, S, Legett, C, Leveille, R, Lewin, E, Little, C, Loche, M, Lopez Reyes, G, Lorenz, R, Lorigny, E, Madariaga, JM, Madsen, M, Mandon, L, Manelski, H, Mangold, N, Martinez, JM, Martin, N, Martinez Frias, J, Maurice, S, Mcconnochie, T, McLennan, S, Melikechi, N, Meslin, PY, Meunier, F, Mimoun, D, Montagnac, G, Montmessin, F, Moros, J, Mousset, V, Murdoch, N, Nelson, T, Newell, R, Nicolas, C, Newsom, H, O’Shea, C, Ollila, A, Pantalacci, P, Parmentier, J, Peret, L, Perrachon, P, Pilleri, P, Pilorget, C, Pinet, P, Poblacion, I, Poulet, F, Quantin Nataf, C, Rapin, W, Reyes, I, Rigaud, L, Robinson, S, Rochas, L, Root, M, Ropert, E, Rouverand, L, Royer, C, Perez, FR, Said, D, Sans-Jofre, P, Schroeder, S, Seel, F, Sharma, S, Sheridan, A, Sobron Sanchez, P, Stcherbinine, A, Stott, A, Toplis, M, Turenne, N, Veneranda, M, Venhaus, D, Wiens, R, Wolf, U & Zastrow, A 2024, 'Radiation-induced alteration of apatite on the surface of Mars: first in situ observations with SuperCam Raman onboard Perseverance', Scientific Reports, vol. 14, 11284. https://doi.org/10.1038/s41598-024-61494-5

APA

Clavé, E., Beyssac, O., Bernard, S., Royer, C., Lopez-Reyes, G., Schröder, S., Rammelkamp, K., Forni, O., Fau, A., Cousin, A., Manrique, J. A., Ollila, A., Madariaga, J. M., Aramendia, J., Sharma, S. K., Fornaro, T., Maurice, S., Wiens, R. C., Acosta-Maeda, T., ... Zastrow, A. (2024). Radiation-induced alteration of apatite on the surface of Mars: first in situ observations with SuperCam Raman onboard Perseverance. Scientific Reports, 14, [11284]. https://doi.org/10.1038/s41598-024-61494-5

Vancouver

Clavé E, Beyssac O, Bernard S, Royer C, Lopez-Reyes G, Schröder S et al. Radiation-induced alteration of apatite on the surface of Mars: first in situ observations with SuperCam Raman onboard Perseverance. Scientific Reports. 2024;14. 11284. https://doi.org/10.1038/s41598-024-61494-5

Author

Clavé, E. ; Beyssac, O. ; Bernard, S. ; Royer, C. ; Lopez-Reyes, G. ; Schröder, S. ; Rammelkamp, K. ; Forni, O. ; Fau, A. ; Cousin, A. ; Manrique, J. A. ; Ollila, A. ; Madariaga, J. M. ; Aramendia, J. ; Sharma, S. K. ; Fornaro, T. ; Maurice, S. ; Wiens, R. C. ; Acosta-Maeda, Tayro ; Agard, Christophe ; Alberquilla, Fernando ; Alvarez Llamas, Cesar ; Anderson, Ryan ; Applin, Daniel ; Aramendia, Julene ; Arana, Gorka ; Beal, Roberta ; Beck, Pierre ; Bedford, Candice ; Benzerara, Karim ; Bernard, Sylvain ; Bernardi, Pernelle ; Bertrand, Tanguy ; Beyssac, Olivier ; Bloch, Thierry ; Bonnet, Jean-Yves ; Bousquet, Bruno ; Boustelitane, Abderrahmane ; Bouyssou Mann, Magali ; Brand, Matthew ; Cais, Philippe ; Caravaca, Gwenael ; De Pinedo, Kepa Castro Ortiz ; Cazalla, Charlene ; Charpentier, Antoine ; Chide, Baptiste ; Clavé, Elise ; Clegg, Samuel ; Cloutis, Ed ; Coloma, Leire ; Comellas, Jade ; Connell, Stephanie ; Cousin, Agnes ; DeFlores, Lauren ; Dehouck, Erwin ; Delapp, Dot ; Perez, Tomas Delgado ; Deron, Robin ; Donny, Christophe ; Doressoundiram, Alain ; Dromart, Gilles ; Essunfeld, Ari ; Fabre, Cecile ; Fau, Amaury ; Fischer, Woodward ; Follic, Hugo ; Forni, Olivier ; Fouchet, Thierry ; Francis, Raymond ; Frydenvang, Jens ; Gabriel, Travis ; Gallegos, Zachary ; García-Florentino, Cristina ; Gasda, Patrick ; Gasnault, Olivier ; Gibbons, Erin ; Gillier, Martin ; Gomez, Laura ; Gonzalez, Sofia ; Grotzinger, John ; Huidobro, Jennifer ; Jacob, Xavier ; Johnson, Jeffrey ; Kalucha, Hemani ; Kelly, Evan ; Knutsen, Elise ; Lacombe, Gaetan ; Lamarque, Florentin ; Lanza, Nina ; Larmat, Carene ; Laserna, Javier ; Lasue, Jeremie ; Le Deit, Laetitia ; Le Mouelic, Stephane ; Legett, Chip ; Leveille, Richard ; Lewin, Eric ; Little, Cynthia ; Loche, Mattéo ; Lopez Reyes, Guillermo ; Lorenz, Ralph ; Lorigny, Eric ; Madariaga, Juan Manuel ; Madsen, Morten ; Mandon, Lucia ; Manelski, Henry ; Mangold, Nicolas ; Martinez, Jose Manrique ; Martin, Noah ; Martinez Frias, Jesus ; Maurice, Sylvestre ; Mcconnochie, Timothy ; McLennan, Scott ; Melikechi, Noureddine ; Meslin, Pierre Yves ; Meunier, Frederique ; Mimoun, David ; Montagnac, Gilles ; Montmessin, Franck ; Moros, Javier ; Mousset, Valerie ; Murdoch, Naomi ; Nelson, Tony ; Newell, Ray ; Nicolas, Cécile ; Newsom, Horton ; O’Shea, Colleen ; Ollila, Ann ; Pantalacci, Philippe ; Parmentier, Jonathan ; Peret, Laurent ; Perrachon, Pascal ; Pilleri, Paolo ; Pilorget, Cédric ; Pinet, Patrick ; Poblacion, Iratxe ; Poulet, Francois ; Quantin Nataf, Cathy ; Rapin, William ; Reyes, Ivan ; Rigaud, Laurent ; Robinson, Scott ; Rochas, Ludovic ; Root, Margaret ; Ropert, Eloise ; Rouverand, Léa ; Royer, Clement ; Perez, Fernando Rull ; Said, David ; Sans-Jofre, Pierre ; Schroeder, Susanne ; Seel, Fabian ; Sharma, Shiv ; Sheridan, Amanda ; Sobron Sanchez, Pablo ; Stcherbinine, Aurélien ; Stott, Alex ; Toplis, Michael ; Turenne, Nathalie ; Veneranda, Marco ; Venhaus, Dawn ; Wiens, Roger ; Wolf, Uriah ; Zastrow, Allison. / Radiation-induced alteration of apatite on the surface of Mars : first in situ observations with SuperCam Raman onboard Perseverance. In: Scientific Reports. 2024 ; Vol. 14.

Bibtex

@article{a39b2dfaa61049789eb172c8ff3c74d9,
title = "Radiation-induced alteration of apatite on the surface of Mars: first in situ observations with SuperCam Raman onboard Perseverance",
abstract = "Planetary exploration relies considerably on mineral characterization to advance our understanding of the solar system, the planets and their evolution. Thus, we must understand past and present processes that can alter materials exposed on the surface, affecting space mission data. Here, we analyze the first dataset monitoring the evolution of a known mineral target in situ on the Martian surface, brought there as a SuperCam calibration target onboard the Perseverance rover. We used Raman spectroscopy to monitor the crystalline state of a synthetic apatite sample over the first 950 Martian days (sols) of the Mars2020 mission. We note significant variations in the Raman spectra acquired on this target, specifically a decrease in the relative contribution of the Raman signal to the total signal. These observations are consistent with the results of a UV-irradiation test performed in the laboratory under conditions mimicking ambient Martian conditions. We conclude that the observed evolution reflects an alteration of the material, specifically the creation of electronic defects, due to its exposure to the Martian environment and, in particular, UV irradiation. This ongoing process of alteration of the Martian surface needs to be taken into account for mineralogical space mission data analysis.",
author = "E. Clav{\'e} and O. Beyssac and S. Bernard and C. Royer and G. Lopez-Reyes and S. Schr{\"o}der and K. Rammelkamp and O. Forni and A. Fau and A. Cousin and Manrique, {J. A.} and A. Ollila and Madariaga, {J. M.} and J. Aramendia and Sharma, {S. K.} and T. Fornaro and S. Maurice and Wiens, {R. C.} and Tayro Acosta-Maeda and Christophe Agard and Fernando Alberquilla and {Alvarez Llamas}, Cesar and Ryan Anderson and Daniel Applin and Julene Aramendia and Gorka Arana and Roberta Beal and Pierre Beck and Candice Bedford and Karim Benzerara and Sylvain Bernard and Pernelle Bernardi and Tanguy Bertrand and Olivier Beyssac and Thierry Bloch and Jean-Yves Bonnet and Bruno Bousquet and Abderrahmane Boustelitane and {Bouyssou Mann}, Magali and Matthew Brand and Philippe Cais and Gwenael Caravaca and {De Pinedo}, {Kepa Castro Ortiz} and Charlene Cazalla and Antoine Charpentier and Baptiste Chide and Elise Clav{\'e} and Samuel Clegg and Ed Cloutis and Leire Coloma and Jade Comellas and Stephanie Connell and Agnes Cousin and Lauren DeFlores and Erwin Dehouck and Dot Delapp and Perez, {Tomas Delgado} and Robin Deron and Christophe Donny and Alain Doressoundiram and Gilles Dromart and Ari Essunfeld and Cecile Fabre and Amaury Fau and Woodward Fischer and Hugo Follic and Olivier Forni and Thierry Fouchet and Raymond Francis and Jens Frydenvang and Travis Gabriel and Zachary Gallegos and Cristina Garc{\'i}a-Florentino and Patrick Gasda and Olivier Gasnault and Erin Gibbons and Martin Gillier and Laura Gomez and Sofia Gonzalez and John Grotzinger and Jennifer Huidobro and Xavier Jacob and Jeffrey Johnson and Hemani Kalucha and Evan Kelly and Elise Knutsen and Gaetan Lacombe and Florentin Lamarque and Nina Lanza and Carene Larmat and Javier Laserna and Jeremie Lasue and {Le Deit}, Laetitia and {Le Mouelic}, Stephane and Chip Legett and Richard Leveille and Eric Lewin and Cynthia Little and Matt{\'e}o Loche and {Lopez Reyes}, Guillermo and Ralph Lorenz and Eric Lorigny and Madariaga, {Juan Manuel} and Morten Madsen and Lucia Mandon and Henry Manelski and Nicolas Mangold and Martinez, {Jose Manrique} and Noah Martin and {Martinez Frias}, Jesus and Sylvestre Maurice and Timothy Mcconnochie and Scott McLennan and Noureddine Melikechi and Meslin, {Pierre Yves} and Frederique Meunier and David Mimoun and Gilles Montagnac and Franck Montmessin and Javier Moros and Valerie Mousset and Naomi Murdoch and Tony Nelson and Ray Newell and C{\'e}cile Nicolas and Horton Newsom and Colleen O{\textquoteright}Shea and Ann Ollila and Philippe Pantalacci and Jonathan Parmentier and Laurent Peret and Pascal Perrachon and Paolo Pilleri and C{\'e}dric Pilorget and Patrick Pinet and Iratxe Poblacion and Francois Poulet and {Quantin Nataf}, Cathy and William Rapin and Ivan Reyes and Laurent Rigaud and Scott Robinson and Ludovic Rochas and Margaret Root and Eloise Ropert and L{\'e}a Rouverand and Clement Royer and Perez, {Fernando Rull} and David Said and Pierre Sans-Jofre and Susanne Schroeder and Fabian Seel and Shiv Sharma and Amanda Sheridan and {Sobron Sanchez}, Pablo and Aur{\'e}lien Stcherbinine and Alex Stott and Michael Toplis and Nathalie Turenne and Marco Veneranda and Dawn Venhaus and Roger Wiens and Uriah Wolf and Allison Zastrow",
note = "Publisher Copyright: {\textcopyright} The Author(s) 2024.",
year = "2024",
doi = "10.1038/s41598-024-61494-5",
language = "English",
volume = "14",
journal = "Scientific Reports",
issn = "2045-2322",
publisher = "nature publishing group",

}

RIS

TY - JOUR

T1 - Radiation-induced alteration of apatite on the surface of Mars

T2 - first in situ observations with SuperCam Raman onboard Perseverance

AU - Clavé, E.

AU - Beyssac, O.

AU - Bernard, S.

AU - Royer, C.

AU - Lopez-Reyes, G.

AU - Schröder, S.

AU - Rammelkamp, K.

AU - Forni, O.

AU - Fau, A.

AU - Cousin, A.

AU - Manrique, J. A.

AU - Ollila, A.

AU - Madariaga, J. M.

AU - Aramendia, J.

AU - Sharma, S. K.

AU - Fornaro, T.

AU - Maurice, S.

AU - Wiens, R. C.

AU - Acosta-Maeda, Tayro

AU - Agard, Christophe

AU - Alberquilla, Fernando

AU - Alvarez Llamas, Cesar

AU - Anderson, Ryan

AU - Applin, Daniel

AU - Aramendia, Julene

AU - Arana, Gorka

AU - Beal, Roberta

AU - Beck, Pierre

AU - Bedford, Candice

AU - Benzerara, Karim

AU - Bernard, Sylvain

AU - Bernardi, Pernelle

AU - Bertrand, Tanguy

AU - Beyssac, Olivier

AU - Bloch, Thierry

AU - Bonnet, Jean-Yves

AU - Bousquet, Bruno

AU - Boustelitane, Abderrahmane

AU - Bouyssou Mann, Magali

AU - Brand, Matthew

AU - Cais, Philippe

AU - Caravaca, Gwenael

AU - De Pinedo, Kepa Castro Ortiz

AU - Cazalla, Charlene

AU - Charpentier, Antoine

AU - Chide, Baptiste

AU - Clavé, Elise

AU - Clegg, Samuel

AU - Cloutis, Ed

AU - Coloma, Leire

AU - Comellas, Jade

AU - Connell, Stephanie

AU - Cousin, Agnes

AU - DeFlores, Lauren

AU - Dehouck, Erwin

AU - Delapp, Dot

AU - Perez, Tomas Delgado

AU - Deron, Robin

AU - Donny, Christophe

AU - Doressoundiram, Alain

AU - Dromart, Gilles

AU - Essunfeld, Ari

AU - Fabre, Cecile

AU - Fau, Amaury

AU - Fischer, Woodward

AU - Follic, Hugo

AU - Forni, Olivier

AU - Fouchet, Thierry

AU - Francis, Raymond

AU - Frydenvang, Jens

AU - Gabriel, Travis

AU - Gallegos, Zachary

AU - García-Florentino, Cristina

AU - Gasda, Patrick

AU - Gasnault, Olivier

AU - Gibbons, Erin

AU - Gillier, Martin

AU - Gomez, Laura

AU - Gonzalez, Sofia

AU - Grotzinger, John

AU - Huidobro, Jennifer

AU - Jacob, Xavier

AU - Johnson, Jeffrey

AU - Kalucha, Hemani

AU - Kelly, Evan

AU - Knutsen, Elise

AU - Lacombe, Gaetan

AU - Lamarque, Florentin

AU - Lanza, Nina

AU - Larmat, Carene

AU - Laserna, Javier

AU - Lasue, Jeremie

AU - Le Deit, Laetitia

AU - Le Mouelic, Stephane

AU - Legett, Chip

AU - Leveille, Richard

AU - Lewin, Eric

AU - Little, Cynthia

AU - Loche, Mattéo

AU - Lopez Reyes, Guillermo

AU - Lorenz, Ralph

AU - Lorigny, Eric

AU - Madariaga, Juan Manuel

AU - Madsen, Morten

AU - Mandon, Lucia

AU - Manelski, Henry

AU - Mangold, Nicolas

AU - Martinez, Jose Manrique

AU - Martin, Noah

AU - Martinez Frias, Jesus

AU - Maurice, Sylvestre

AU - Mcconnochie, Timothy

AU - McLennan, Scott

AU - Melikechi, Noureddine

AU - Meslin, Pierre Yves

AU - Meunier, Frederique

AU - Mimoun, David

AU - Montagnac, Gilles

AU - Montmessin, Franck

AU - Moros, Javier

AU - Mousset, Valerie

AU - Murdoch, Naomi

AU - Nelson, Tony

AU - Newell, Ray

AU - Nicolas, Cécile

AU - Newsom, Horton

AU - O’Shea, Colleen

AU - Ollila, Ann

AU - Pantalacci, Philippe

AU - Parmentier, Jonathan

AU - Peret, Laurent

AU - Perrachon, Pascal

AU - Pilleri, Paolo

AU - Pilorget, Cédric

AU - Pinet, Patrick

AU - Poblacion, Iratxe

AU - Poulet, Francois

AU - Quantin Nataf, Cathy

AU - Rapin, William

AU - Reyes, Ivan

AU - Rigaud, Laurent

AU - Robinson, Scott

AU - Rochas, Ludovic

AU - Root, Margaret

AU - Ropert, Eloise

AU - Rouverand, Léa

AU - Royer, Clement

AU - Perez, Fernando Rull

AU - Said, David

AU - Sans-Jofre, Pierre

AU - Schroeder, Susanne

AU - Seel, Fabian

AU - Sharma, Shiv

AU - Sheridan, Amanda

AU - Sobron Sanchez, Pablo

AU - Stcherbinine, Aurélien

AU - Stott, Alex

AU - Toplis, Michael

AU - Turenne, Nathalie

AU - Veneranda, Marco

AU - Venhaus, Dawn

AU - Wiens, Roger

AU - Wolf, Uriah

AU - Zastrow, Allison

N1 - Publisher Copyright: © The Author(s) 2024.

PY - 2024

Y1 - 2024

N2 - Planetary exploration relies considerably on mineral characterization to advance our understanding of the solar system, the planets and their evolution. Thus, we must understand past and present processes that can alter materials exposed on the surface, affecting space mission data. Here, we analyze the first dataset monitoring the evolution of a known mineral target in situ on the Martian surface, brought there as a SuperCam calibration target onboard the Perseverance rover. We used Raman spectroscopy to monitor the crystalline state of a synthetic apatite sample over the first 950 Martian days (sols) of the Mars2020 mission. We note significant variations in the Raman spectra acquired on this target, specifically a decrease in the relative contribution of the Raman signal to the total signal. These observations are consistent with the results of a UV-irradiation test performed in the laboratory under conditions mimicking ambient Martian conditions. We conclude that the observed evolution reflects an alteration of the material, specifically the creation of electronic defects, due to its exposure to the Martian environment and, in particular, UV irradiation. This ongoing process of alteration of the Martian surface needs to be taken into account for mineralogical space mission data analysis.

AB - Planetary exploration relies considerably on mineral characterization to advance our understanding of the solar system, the planets and their evolution. Thus, we must understand past and present processes that can alter materials exposed on the surface, affecting space mission data. Here, we analyze the first dataset monitoring the evolution of a known mineral target in situ on the Martian surface, brought there as a SuperCam calibration target onboard the Perseverance rover. We used Raman spectroscopy to monitor the crystalline state of a synthetic apatite sample over the first 950 Martian days (sols) of the Mars2020 mission. We note significant variations in the Raman spectra acquired on this target, specifically a decrease in the relative contribution of the Raman signal to the total signal. These observations are consistent with the results of a UV-irradiation test performed in the laboratory under conditions mimicking ambient Martian conditions. We conclude that the observed evolution reflects an alteration of the material, specifically the creation of electronic defects, due to its exposure to the Martian environment and, in particular, UV irradiation. This ongoing process of alteration of the Martian surface needs to be taken into account for mineralogical space mission data analysis.

U2 - 10.1038/s41598-024-61494-5

DO - 10.1038/s41598-024-61494-5

M3 - Journal article

C2 - 38760365

AN - SCOPUS:85193534997

VL - 14

JO - Scientific Reports

JF - Scientific Reports

SN - 2045-2322

M1 - 11284

ER -

ID: 393289463