Structural and magnetic behavior of a quasi-1D antiferromagnetic chain compound Cu(NCS)2(pyz)

Research output: Contribution to journal › Journal article › Research › peer-review

Standard

Structural and magnetic behavior of a quasi-1D antiferromagnetic chain compound Cu(NCS)2(pyz). / Bordallo, H. N.; Chapon, L.; Manson, J. L.; Ling, C. D.; Qualls, J. S.; Hall, D.; Argyriou, D. N.

In: Polyhedron, Vol. 22, No. 14-17, 15.07.2003, p. 2045-2049.

Research output: Contribution to journal › Journal article › Research › peer-review

Harvard

Bordallo, HN, Chapon, L, Manson, JL, Ling, CD, Qualls, JS, Hall, D & Argyriou, DN 2003, 'Structural and magnetic behavior of a quasi-1D antiferromagnetic chain compound Cu(NCS)2(pyz)', Polyhedron, vol. 22, no. 14-17, pp. 2045-2049. https://doi.org/10.1016/S0277-5387(03)00188-8

APA

Bordallo, H. N., Chapon, L., Manson, J. L., Ling, C. D., Qualls, J. S., Hall, D., & Argyriou, D. N. (2003). Structural and magnetic behavior of a quasi-1D antiferromagnetic chain compound Cu(NCS)2(pyz). Polyhedron, 22(14-17), 2045-2049. https://doi.org/10.1016/S0277-5387(03)00188-8

Vancouver

Bordallo HN, Chapon L, Manson JL, Ling CD, Qualls JS, Hall D et al. Structural and magnetic behavior of a quasi-1D antiferromagnetic chain compound Cu(NCS)2(pyz). Polyhedron. 2003 Jul 15;22(14-17):2045-2049. https://doi.org/10.1016/S0277-5387(03)00188-8

Author

Bordallo, H. N. ; Chapon, L. ; Manson, J. L. ; Ling, C. D. ; Qualls, J. S. ; Hall, D. ; Argyriou, D. N. / Structural and magnetic behavior of a quasi-1D antiferromagnetic chain compound Cu(NCS)2(pyz). In: Polyhedron. 2003 ; Vol. 22, No. 14-17. pp. 2045-2049.

Bibtex

@article{b38d772bd4ca421887bdff34f3eb08d6,
title = "Structural and magnetic behavior of a quasi-1D antiferromagnetic chain compound Cu(NCS)2(pyz)",
abstract = "Synchrotron X-ray diffraction (XRD) and neutron powder diffraction (NPD) were used to determine the structure of Cu(NCS)2(pyz) (pyz = pyrazine = C4N2H4), which consists of a stacking of Cu-pyz-Cu chains. While NPD measurements showed no evidence of long-range magnetic ordering, the temperature dependence of the magnetic susceptibility and magnetization suggests that the system can be adequately described on the local scale as a spin-1/2 antiferromagnet (AFM) chain with an intrachain exchange interaction J/kB = -8 K (∼0.7 meV). Comparison of isothermal magnetization data acquired up to 30 T at 1.6 K to a linear chain model shows excellent agreement, making this material a nearly ideal example of an isotropic Heisenberg AFM chain.",
keywords = "Copper, Neutron powder diffraction, Pyrazine, Quantum spin chain, X-ray diffraction",
author = "Bordallo, {H. N.} and L. Chapon and Manson, {J. L.} and Ling, {C. D.} and Qualls, {J. S.} and D. Hall and Argyriou, {D. N.}",
year = "2003",
month = jul,
day = "15",
doi = "10.1016/S0277-5387(03)00188-8",
language = "English",
volume = "22",
pages = "2045--2049",
journal = "Polyhedron",
issn = "0277-5387",
publisher = "Pergamon Press",
number = "14-17",

}

RIS

TY - JOUR

T1 - Structural and magnetic behavior of a quasi-1D antiferromagnetic chain compound Cu(NCS)2(pyz)

AU - Bordallo, H. N.

AU - Chapon, L.

AU - Manson, J. L.

AU - Ling, C. D.

AU - Qualls, J. S.

AU - Hall, D.

AU - Argyriou, D. N.

PY - 2003/7/15

Y1 - 2003/7/15

N2 - Synchrotron X-ray diffraction (XRD) and neutron powder diffraction (NPD) were used to determine the structure of Cu(NCS)2(pyz) (pyz = pyrazine = C4N2H4), which consists of a stacking of Cu-pyz-Cu chains. While NPD measurements showed no evidence of long-range magnetic ordering, the temperature dependence of the magnetic susceptibility and magnetization suggests that the system can be adequately described on the local scale as a spin-1/2 antiferromagnet (AFM) chain with an intrachain exchange interaction J/kB = -8 K (∼0.7 meV). Comparison of isothermal magnetization data acquired up to 30 T at 1.6 K to a linear chain model shows excellent agreement, making this material a nearly ideal example of an isotropic Heisenberg AFM chain.

AB - Synchrotron X-ray diffraction (XRD) and neutron powder diffraction (NPD) were used to determine the structure of Cu(NCS)2(pyz) (pyz = pyrazine = C4N2H4), which consists of a stacking of Cu-pyz-Cu chains. While NPD measurements showed no evidence of long-range magnetic ordering, the temperature dependence of the magnetic susceptibility and magnetization suggests that the system can be adequately described on the local scale as a spin-1/2 antiferromagnet (AFM) chain with an intrachain exchange interaction J/kB = -8 K (∼0.7 meV). Comparison of isothermal magnetization data acquired up to 30 T at 1.6 K to a linear chain model shows excellent agreement, making this material a nearly ideal example of an isotropic Heisenberg AFM chain.

KW - Copper

KW - Neutron powder diffraction

KW - Pyrazine

KW - Quantum spin chain

KW - X-ray diffraction

UR - http://www.scopus.com/inward/record.url?scp=0041804376&partnerID=8YFLogxK

U2 - 10.1016/S0277-5387(03)00188-8

DO - 10.1016/S0277-5387(03)00188-8

M3 - Journal article

AN - SCOPUS:0041804376

VL - 22

SP - 2045

EP - 2049

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

IS - 14-17

ER -

ID: 210118217