TY - JOUR

T1 - Arctic mercury flux increased through the Last Glacial Termination with a warming climate

AU - Segato, Delia

AU - Saiz-Lopez, Alfonso

AU - Mahajan, Anoop Sharad

AU - Wang, Feiyue

AU - Corella, Juan Pablo

AU - Cuevas, Carlos Alberto

AU - Erhardt, Tobias

AU - Jensen, Camilla Marie

AU - Zeppenfeld, Chantal

AU - Kjaer, Helle Astrid

AU - Turetta, Clara

AU - Cairns, Warren Raymond Lee

AU - Barbante, Carlo

AU - Spolaor, Andrea

PY - 2023/5/4

Y1 - 2023/5/4

N2 - Mercury deposition onto the Greenland Ice Sheet increased from the Last Glacial Termination to early Holocene as the North Atlantic warmed and sea ice retreated, according to an ice-core mercury record and atmospheric chemistry modelling.Mercury is a pollutant of global concern, especially in the Arctic, where high levels are found in biota despite its remote location. Mercury is transported to the Arctic via atmospheric, oceanic and riverine long-range pathways, where it accumulates in aquatic and terrestrial ecosystems. While present-day mercury deposition in the Arctic from natural and anthropogenic emissions is extensively studied, the control of past climate changes on natural mercury variability remains unknown. Here we present an Arctic mercury record covering the Last Glacial Termination to the early Holocene epoch (15.7-9.0 thousand years before 2000 ce), collected as part of the East Greenland Ice-Core Project. We find a threefold increase in mercury depositional fluxes from the Last Glacial Termination into the early Holocene, which coincided with abrupt regional climate warming. Atmospheric chemistry modelling, combined with available sea-ice proxies, indicates that oceanic mercury evaporation and atmospheric bromine drove the increase in mercury flux during this climatic transition. Our results suggest that environmental changes associated with climate warming may contribute to increasing mercury levels in Arctic ecosystems.

AB - Mercury deposition onto the Greenland Ice Sheet increased from the Last Glacial Termination to early Holocene as the North Atlantic warmed and sea ice retreated, according to an ice-core mercury record and atmospheric chemistry modelling.Mercury is a pollutant of global concern, especially in the Arctic, where high levels are found in biota despite its remote location. Mercury is transported to the Arctic via atmospheric, oceanic and riverine long-range pathways, where it accumulates in aquatic and terrestrial ecosystems. While present-day mercury deposition in the Arctic from natural and anthropogenic emissions is extensively studied, the control of past climate changes on natural mercury variability remains unknown. Here we present an Arctic mercury record covering the Last Glacial Termination to the early Holocene epoch (15.7-9.0 thousand years before 2000 ce), collected as part of the East Greenland Ice-Core Project. We find a threefold increase in mercury depositional fluxes from the Last Glacial Termination into the early Holocene, which coincided with abrupt regional climate warming. Atmospheric chemistry modelling, combined with available sea-ice proxies, indicates that oceanic mercury evaporation and atmospheric bromine drove the increase in mercury flux during this climatic transition. Our results suggest that environmental changes associated with climate warming may contribute to increasing mercury levels in Arctic ecosystems.

KW - HIGH-RESOLUTION RECORD

KW - SEA-ICE

KW - ATMOSPHERIC MERCURY

KW - FRAM STRAIT

KW - HOLOCENE

KW - GREENLAND

KW - PEAT

KW - ACCUMULATION

KW - DEPOSITION

KW - CHEMISTRY

U2 - 10.1038/s41561-023-01172-9

DO - 10.1038/s41561-023-01172-9

M3 - Journal article

VL - 16

SP - 439

EP - 445

JO - Nature Geoscience

JF - Nature Geoscience

SN - 1752-0894

ER -